Measurement and Prediction of the Thermal Conductivity of Tricyanomethanide- and Tetracyanoborate-Based Imidazolium Ionic Liquids

Thermophysical properties of aqueous solutions of the 1-ethyl-3-methylimidazolium tricyanomethanide ionic liquid

“…The viscosity determinations show generally much greater disparities; here our measurements agree best with those of Domań ska et al [19], while the most recent data of Ganbold et al [18], which can be unfortunately considered less reliable because of unknown water content in their sample, deviate the most. The value of refractive index at T = 298.15 K measured by us for pure [EMIM][TCM] (n D ¼ 1:51227) agrees within experimental uncertainty with those determined by Fröba et al [17] (n D ¼ 1:51217, linearly interpolated between T = (293.15 and 303.15) K) and Neves et al [16] (n D ¼ 1:51236), but the value (n D ¼ 1:5116) interpolated from measurements of Koller et al [14] deviates significantly.…”

Thermophysical properties of imidazolium tricyanomethanide ionic liquids: experiments and molecular simulation

“…2,49,50 Some thermophysical properties for imidazolium [TCM] À -based ILs have been recently reported in the literature. 56, 57 Neves et al 58 performed for the first time a consistent and comprehensive structure-property study for a set of imidazolium-based ILs with cyano-functionalized anions, where the effect of the anion on the studied properties was investigated. However, the effect of the chemical nature of those ILs and their impact on the structural segregation of ILs is not clear.…”

“…The representation of the densities at 298.15 K against the molar mass of the anion is shown in Fig. 3 56 were also considered.…”

Surface tension and 0.1MPa density for members of homologous series of ionic liquids composed of imidazolium-, pyridinium-, and pyrrolidinium-based cations and of cyano-groups containing anions

“…(4), dimensionless temperature variable θ = T /([C 2 MIM][TCM]: Relative deviations 10 2 · (̺ exp /̺ calc − 1) of the experimental density data, ̺ exp ,from the values ̺ calc calculated from the correlation equation(4)as a function of temperature T . , Fröba et al[11]; △, Królikowski et al[13]; ⊲, Larriba et al[14]; +, Neves et al[15]; ♦, Koller et al[16]; * ,Larriba et al [17]; •, this work. Data from Refs.…”

“…Tables 1 and 2 give an overview of the data sources [1], [11]- [25] available in the literature on 0.1 MPa density and surface tension of the four tricyanomethanides of interest. Among the properties of the four ionic liquids, the density of [C 2 MIM][TCM] [1], [11]- [17] and of [C 4 MIM][TCM] [12], [15], [16], [18], [19] and [25] have been most studied. For [C 4 MPYR][TCM], 18 data points in temperature range from (298 to 363) K have been published by Domańska et al [20]- [22].…”