Measurement and prediction of bubble point pressure of a novel solvent with propellant for color spray

Some mixing rules were proposed with simple functional form to predict binary gas mixture solubility in pure solvent/pure gas solubility in binary solvent mixture. The experimental data employed were those of Tsuji et al. (2019) for equimolar binary gas mixture (nitrogen (N2) + oxygen (O2)) solubility in styrene at 303 K, and of Tsuji et al. (2005) for hydrogen (H2) solubility in equimolar mixture of benzene + cyclohexane at 303 K. These solubilities have a linear pressure dependence like Henry’s law at least up to 4.827 MPa. To predict gas solubilities, the mixing rules were proposed for Henry constant of gas mixtures in pure solvent and that of pure gas in solvent mixture just by using Henry constant of pure gas in pure solvent without any binary parameter. The function form was similar to that of van der Waals one fluid model, Q = ∑i ∑j zi zj Q ij for the mole ratio of constituent of gas or solvent mixture, zi. The Q = H and Q ij = (H i + H j )/2 show the best reproducibility for (N2 + O2) solubility in styrene with average absolute relative deviation (AARD) 0.667 %. Otherwise, the Q = 1/H and Q ij = (1/H i + 1/H j )/2 show the best reproducibility for H2 solubility in benzene + cyclohexane with AARD 5.605 %. The results were well described by a universality of physical properties and Lorentz-Berthelot theorem.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Measurement and prediction of bubble point pressure of a novel solvent with propellant for color spray

Cited by 4 publications

References 22 publications

Bubble point pressures of binary mixtures of ethanol with propane, dimethyl ether or trans-1,3,3,3-tetrafluoropropene and correlation with equations of state and Wong-Sandler mixing rules

Bubble point pressures of binary mixtures of ethanol with propane, dimethyl ether or trans-1,3,3,3-tetrafluoropropene and correlation with equations of state and Wong-Sandler mixing rules

Numerical investigation on supersaturation phenomenon of humid air in the humidification process

Evaluation of Henry Constant for Gas / Gas Mixture in Pure and Solvent Mixture Using Simple Functional Mixing Rule

Contact Info

Product

Resources

About