This paper deals with the medium-voltage (MV) power line communication (PLC) in the context of energy harvesting. To do so, a measurement campaign was carried out in urban and rural environments of Curitiba city, Brazil. This measurement campaign estimated the MV-PLC additive noise in these electric power networks. Numerical results show that the mean power, for distinct RF-to-DC conversion factors, in the urban environment is higher than in the rural one. Also, the achievable data rate analysis over the MV electric power networks shows the usefulness of this additive noise for feeding low-bit-rate devices.