1998
DOI: 10.1016/s0301-0104(98)00238-9
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Matrix photochemistry of nitrosyl chloride.

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Cited by 27 publications
(42 citation statements)
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“…Figure 2 b shows a cut for r NO =2.15 bohr. The key features here are the two wells, one of which is at the Franck–Condon (FC) geometry and the other further out, centred at about r ClN =5.7 bohr, r NO =2.1 bohr and θ =40°, which corresponds to the ClON isomer [39]. This second well arises due to an interaction with the 2 1 A′ state occurring around θ =70° throughout the surface.…”
Section: Resultsmentioning
confidence: 92%
“…Figure 2 b shows a cut for r NO =2.15 bohr. The key features here are the two wells, one of which is at the Franck–Condon (FC) geometry and the other further out, centred at about r ClN =5.7 bohr, r NO =2.1 bohr and θ =40°, which corresponds to the ClON isomer [39]. This second well arises due to an interaction with the 2 1 A′ state occurring around θ =70° throughout the surface.…”
Section: Resultsmentioning
confidence: 92%
“…25,36,[39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56] In contrast, the structural isomer (ClON) is the only photoproduct observed in low-temperature matrix studies. 63,64 The results presented here represent the first detailed measurements of ClNO photochemistry in solution. The experimentally observed opticaldensity evolution that occurs following ClNO photolysis demonstrates that a photoproduct is formed that has an absorption maximum of 295 nm in acetonitrile and 330 nm in chloroform.…”
Section: Discussionmentioning
confidence: 88%
“…Specifically, the NO-stretch fundamental transition (ν 1 ) does not change significantly between gasphase (1799.7 cm -1 ) and Ar matrixes (1805 cm -1 ); however, the bend and ClN fundamental transitions shift from 596 cm -1 (ν 2 ) and 332 cm -1 (ν 3 ) in the gas phase to 585 cm -1 (ν 2 ) and 319 cm -1 (ν 3 ) in an Ar-matrix, respectively. 63,64,82 In solution, the ν 2 and ν 3 fundamental transitions shift from 585 and 325 cm -1 in cyclohexane to 545 and 310 cm -1 in acetonitrile. 65,66 With respect to the structural isomer, ClON is predicted to have an even shorter NO bond length (1.127 Å) than diatomic NO whereas the ClO bond length is predicted to be extremely long (2.273 Å).…”
Section: Discussionmentioning
confidence: 99%
“…[15][16][17][18][19] für eine Diskussion von Schweratom-Tunneleffekten in der Cyclobutadien-Automerisation (Lit. [20]) und die etwas skeptischere Sicht in Lit. [21] für Tunneleffekte in Isonitrosylchlorid sowie Lit.…”
Section: Derkürzestewegzueinemtalaufderunclassified