Matrix Acidizing: A Laboratory and Field Investigation of Sludge Formation and Removal of Oil-Based Drilling Mud Filter Cake

Abstract

Summary Hydrochloric and organic acids have been extensively used to enhance well productivity or injectivity in tight carbonate formations (10 to 50 md). The use of these acids, however, can cause instances of complete production loss. This is especially common due to incompatibilities of the acidizing fluid and oil, which can lead to the formation of acid/oil emulsions and sludge formation. Consequently, it is necessary to properly identify and remove such emulsions or precipitations without causing any further damage. Compatibility studies were conducted using representative crude samples and hydrochloric acid (HCl). The experiments were conducted at various temperatures up to 240°F using high-pressure/high-temperature (HP/HT) aging cells for both live and spent acid samples, in which some of the experiments included an antisludge, an iron-control agent, and a demulsifier. In addition, another set of experiments was performed in the presence of ferric ions (Fe3+). The total iron concentration in these experiments was varied between 0 and1,000 ppm. The results showed that commonly used acid systems were not compatible with representative oil field samples. The amount of sludge formed and the stability of formed emulsions increased significantly in the presence of ferric ions and was more severe in the presence of hydrogen sulfide (H2S). Using a field case, this paper will cover the methodology used to ascertain the source of formation damage from acidizing, study the different factors that influence the formation of acid/oil emulsion and sludge formation mechanism, and show how they can be removed. In this example, acid/oil emulsions, sludge formation, and improper drilling mud filter-cake removal were the reasons behind the production loss. However, the methodology can be expanded to cater the many acidizing failure cases faced in the industry worldwide.

Chelating Agents in the Oilfield

“…The chelating properties of chelating agents can be used to tackle another major problem in the oil and gas industry, namely iron. Ferric (Fe 3+ ) iron has a reputation for causing many issues during stimulation treatments by stabilizing damaging emulsions and inducing the precipitation of sludge and asphaltene [40,41]. Iron has also been found to be incompatible with several additives used in the oil industry, including viscoelastic surfactants (VES).…”

Perspective Chapter: Downhole Corrosion in the Oilfield

“…This will damage the tubulars and result in "face dissolution" toward the formation rock, thus, compromising its ability to generate wormholes that can bypass the damage zones downhole [30]. Furthermore, it has the potential to cause sludge and asphaltene precipitation if mixed with an incompatible crude [31]. On the other hand, organic acids have a lower tendency to form sludge and emulsion when mixed with crude oil.…”