Large-scale
production of hydrogen (H2) calls for the
development of technology that abates environmental pollution in order
to attain energy sustainability. Heat-generating chemicals, herein
referred to as thermochemical fluids (TCFs), offer the advantage of
steam generation for stimulating highly viscous oil, such as bitumen.
The aim of this investigation is to explore H2 production
through gasification of TCF-stimulated bitumen under CO2-rich oxidants (100_CO2: 100% CO2, 50_CO2: mixture of 50% CO2, and 50% O2), compared
with air (mixture of 21% O2 and 79% N2) and
OxyFuel (100% O2). Kinetic data from TCF reactions and
those of thermogravimetric analysis of TCF-treated bitumen have been
incorporated with relevant gasification reaction models to build a
zero-dimensional steady-state thermodynamic model to simulate gasification
using the Aspen HYSYS software. The TCF rate kinetics can be modeled
using the second-order rate law with the activation energy E
TCF calculated to be 77.5 kJ/mol and the frequency
factor A
TCF obtained to be 4.47 ×
106 (mol/dm3)−1 (s–1). Sensitivity studies were performed considering bitumen, oxidant,
and TCF mass flow rates as input variables. The results generally
revealed the potential to generate a significant fraction of H2. It was also revealed that a higher H2 fraction
could be produced under 100% CO2 oxidants compared with
others, while higher CH4 as well as CO gases could be generated
under the OxyFuel oxidant. However, it was found that a higher CO2 pollutant would be produced under 100% CO2 gasification.
Likewise, considering the sensitivity to oxidant feeds, it was found
that the system could generate relatively low Na2SO4 pollutants with a higher fraction under OxyFuel as well as
50_CO2 oxidant gas.