The
free-standing Ni–Al2O3 ensemble
derived from NiAl-layered double hydroxides (NiAl-LDHs) grown onto
a Ni-foam has been developed for the exothermic gas-phase acetone
hydrogenation to isopropanol. This approach works effectively and
efficiently to achieve a unique combination of high activity/selectivity
and enhanced heat/mass transfer stemmed from the Ni-foam. The outstanding
catalyst is obtained by direct reduction of the un-calcined NiAl-LDH/Ni-foam,
with a high turnover frequency of 0.90 s–1, being
capable of converting 90.8% acetone into isopropanol with almost 100%
selectivity under stoichiometric H2/acetone molar ratio,
atmospheric pressure at 80 °C, and a WHSVacetone of
10 h–1. The catalyst derivation using the un-calcined
NiAl-LDH/Ni-foam enables the Ni nanoparticles to be intertwined with
Al2O3 to form a large Ni–Al2O3 interface, without interruption of impurities such
as irreducible NiO (in the case of calcined NiAl-LDH/Ni-foam samples),
which markedly improves the strong acetone adsorption next to the
Ni0 hydrogenation sites, thereby leading to a dramatic
improvement of catalyst activity.