Abstract. Shock-wave data are now available for a variety of rocks, minerals, and oxides of geophysical interest in the pressure range appropriate for the lower mantle. These data are analyzed to obtain equation-of-state parameters with emphasis on the shock-induced high-pressure phases. Of twenty-four materials for which Hugoniot data are analyzed, all but MgO, AlzO,, and Mn02 undergo at least one shock-induced phase change below 800 kb. Birch-Murnaghan parameters for the raw Hugoniots, metastable Hugoniots, adiabats, and 25°C isotherms are obtained for the high-pressure phases. On correcting the raw Hugoniot data for MgO and ALOa for strength effects, we find that the calculated adiabatic equations of state are in good agreement with recent ultrasonic data. The zero-pressure densities of high-pressure phases are obtained by constraining the adiabats calculated from the Hugoniot data such that the zero~ pressure densities and the zero-pressure slopes of the adiabats satisfy Anderson's seismic equation of state.Probable crystallographic stmcturcs of the high-pressure phases are inferred from the classical laws of crystal chemistry and, in some cases, from static high-pressure recovery experiments on analog compounds. Shock data for Si02 (stishovite) indicate that transformation to the fluorite-type structure (observed in TiO,) does not take place under shock, at least to -2000 kb. Fe203 probably transforms to either the perovskite or B rare earth structure with a zero-pressure density of 5.96 g/cm 3 • MgAl20• (spinel) may transform to the CaFe20< structure with a zero-pressure density of 4.19 g/cm 3 • 1 Contribution 1571, Division of Geological Sciences, California Institute of Technology, Pasadena.2 On leave from Australian National University, Canberra, Australia.Copyright © 1969 by the American Geophysical Union.
668 AHRENS, ANDERSON, AND RINGWOODFeldspars transform to the hollandite structure (density, of -3.85 g/cm 3 ). Olivine-rich rocks containing greater than 10% FeO either disproportionate to the ilmenite and rock salt structure or transform to a new post-spinel polymorph having the Sr.2PbO. structure. Pyroxenes containing greater than 10% FeO probably transform to the ilmenite structure. High-pressure forms of sillimanite and andalusite have calculated densities of 4.00 and 3.95 g/cm", respectively. This probably represents disproportionation reaction products, A10s + Si02 (stishovite), which would give a density of 4.09 g/cm 3 •The Birch-Murnaghan second-order parameter ~ is nearly zero for MgO and AI.Oa. 0.73 for stishovite, and -1 for the high-pressure phases of the olivines and pyroxenes.