Material qualification of a 13Cr-L80 casing for sour conditions

Abstract

This work aims to determine the material qualification of 13Cr-L80 casing for sour conditions which is of great importance to check the sulfide stress cracking susceptibility, confirm the range of applicable conditions and recommend anti-corrosion materials. First, the casing material was tested to judge whether its properties were normal. Secondly, the testing matrix was defined to determine actual casing exposure conditions. Thirdly, slow strain rate testing was used to screen the conditions. Fourthly, thirty-day tests of uniaxial tensile specimens were conducted to check for SSC susceptibility. The casing material satisfied API 5CT standards and could be used for slow strain rate testing and sulfide stress cracking testing. The testing matrix is intended to distinguish the combined effect of temperatures (41, 75, 140 °F), chloride levels (1000, 13 000 mg × L−1), pH (3.5, 5.5) and partial pressures of H2S (3.5 psi) in shut-in and flowing conditions. The slow strain rate testing showed a reduction of signs of embrittlement with increased temperature, suggesting that the mechanism is supported by sulfide stress cracking. The 13Cr-L80 passed field-specific qualification tests for sulfide stress cracking resistance in sour wells at maximum H2S partial pressures of 3.5 psi in the casing-tubing annulus. The API 5CT 13Cr-L80 casing application is in compliance with ISO15156/NACE MR0175 standards as long as the aggressiveness of the field conditions does not go beyond the envelope conditions tested (3.5 psi of H2S, pH 3.5, temperature of 41 or 75 °F).

Effect of Surface Roughness on Static Corrosion Behavior of J55 Carbon Steel in CO2-Containing Geothermal Water at 65 °C

“…Therefore, it is able to protect the surface of carbon steel and reduce the corrosion rate. Under Sa = 1.112 µm conditions, the corrosion product layer covers the pits formed during the initial stage of corrosion, forming a "occluded cell", which intensifies the pitting rate [48].…”