Massively Reconstructing Hydrogen Bonding Network and Coordination Structure Enabled by a Natural Multifunctional Co‐Solvent for Practical Aqueous Zn‐Ion Batteries

Abstract

The practical application of aqueous Zn‐ion batteries (AZIBs) is hindered by the crazy Zn dendrites growth and the H2O‐induced side reactions, which rapidly consume the Zn anode and H2O molecules, especially under the lean electrolyte and Zn anode. Herein, a natural disaccharide, d‐trehalose (DT), is exploited as a novel multifunctional co‐solvent to address the above issues. Molecular dynamics simulations and spectral characterizations demonstrate that DT with abundant polar −OH groups can form strong interactions with Zn2+ ions and H2O molecules, and thus massively reconstruct the coordination structure of Zn2+ ions and the hydrogen bonding network of the electrolyte. Especially, the strong H‐bonds between DT and H2O molecules can not only effectively suppress the H2O activity but also prevent the rearrangement of H2O molecules at low temperature. Consequently, the AZIBs using DT30 electrolyte can show high cycling stability even under lean electrolyte (E/C ratio = 2.95 µL mAh−1), low N/P ratio (3.4), and low temperature (−12 °C). As a proof‐of‐concept, a Zn||LiFePO4 pack with LiFePO4 loading as high as 506.49 mg can be achieved. Therefore, DT as an eco‐friendly multifunctional co‐solvent provides a sustainable and effective strategy for the practical application of AZIBs.