Multi-connectivity (MC) is one of the most important features to be introduced in 5G networks, allowing User Equipment (UE) to simultaneously aggregate radio resources from several network nodes to enhance both data rates and reliability. Thus, this feature enables a further flexibility in the allocation of resources to the UEs in order to fulfil the users’ requirements in more complex 5G scenarios. This paper takes advantage of this wide flexibility to present a traffic steering approach that determines the amount of traffic to be held by each of the serving nodes in a multi-connectivity scenario. In this sense, the proposed technique is based on network and UE performance metrics in order to maximize the users’ perceived quality of experience (QoE) for enhanced Mobile Broadband (eMBB) services. It is then compared with a homogeneous traffic split among the serving nodes, with a single-connectivity approach and with state-of-the-art solutions. The benefits are analysed in terms of throughput and Mean Opinion Score (MOS), which is the main QoE metric. The analysis shows that a noticeable UE throughput improvement is reached when the proposed traffic steering method is applied. Consequently, this enhancement is noticed in the users’ QoE, which can lead to a reduction of operating expenses (OPEX) of the network.