The surface rejuvenation model of the turbulent burst process, already developed for the momentum and heat transfer processes, is applied to the field of mass transfer. The range of applicability of the theory, previously shown to be valid for the Prandtl number range 0.7 to 64 is extended to Schmidt numbers of 6,500 without introducing any new parameters. Concentration and temperature profiles for high Schmidt and Prandtl numbers are in agreement with experimental data. Theoretical expressions for Sherwood and Stanton numbers are calculated and shown to be in agreement with experimental data over five orders of magnitude.
CONCLUSIONS AND SIGNIFICANCEA turbulent burst or surface rejuvenation model has been developed in this study for mass or heat transfer to fluids with values of Sc or Pr up to lo4. In this approach, the actual unsteady process that occurs between inrush and ejection phases of a burst event is modeled, with the approach distance distri- which is in agreement with experimental data for Sc from 0.5 to 10,000. The analysis indicates that the thickness of the unrepIenished layer of fluid existing at the surface is significant for values of Sc much greater than 5. For values of Sc less than about 5, this layer occupies less than 10% of the molecular wall region, such that the simple surface renewal model can be used.Based on the results of this analysis and on earlier work, it is concluded that the surface rejuvenation model provides a useful
Page 1614October, 1985 AlChE Journal (Vol. 31, No. 10) alternative approach to characterizing the wall region for moderate to high values of Sc and Pr. Because of the strong physical basis for the surface rejuvenation model, and as this approach involves a minimum level of empiricism, the theory is believed to provide a fundamental basis for generalization to other transport processes involving wall turbulence.