Abstract.A prominent set of veins was formed during post-metamorphic deformation of the Caledonian Dalradian metamorphic belt. These veins are concentrated in dilational zones in fold hinges, but apophyses follow schistosity and fold axial surface fractures. The veins are most common in the cores of regional structures, especially the Dalradian Downbend and consist of quartz, calcite, chlorite and metallic sulphides and oxides. Metals, including gold, have been concentrated in the veins. The fluid which formed the veins was low salinity (1 -5 wt% NaC1 and KCI) COg-bearing (3-16 wt% CO2) water of metamorphic origin. The fluid varies slightly in composition within and between samples, but is essentially uniform in composition over several hundred km 2. Vein formation occurred at about 350+50~ and 200-300 MPa pressure. Further quartz mineralization occurred in some dilational zones at lower temperatures (160-180 ~ This later mineralization was accompanied by CO2 immiscibility. Dilution and oxidation of the metamorphic fluid occurred due to mixing with meteoric water as the rocks passed through the brittle-ductile transition. A similar metamorphic fluid is thought to have been responsible for gold mineralization in the nearby Tyndrum Fault at a later stage in the Dalradian uplift.Late Caledonian, post-metamorphic, metalliferous veins commonly occur in the Caledonian Dalradian metamorphic belt. Many of these veins are clearly associated with magmatic processes (Plant et al. 1983;Alderton 1985), but for others, the origin of the mineralizing fluid is not so clear (Pattrick et al. 1988). It is the purpose of this paper to show that metamorphic fluids formed an important part of the hydrothermal fluid flux through the Dalradian rocks in late Caledonian times, that these fluids carried metals, and that at least some of the post-meta-* Present address: Geology Department, University of Otago, P.O. Box 56, Dunedin, New Zealand morphic metalliferous deposits, particularly Au-bearing ones, may have been formed from such fluids.Fluid movement during uplift of a metamorphic belt is a well-established phenomenon. Fluids have been investigated in active mountain belts (Pecher 1979;Craw 1987;Holm et al. 1989), and in more deeply eroded belts (Hollister and Burruss 1976;Crawford et al. 1979), principally by fluid inclusion studies of veins. In most such studies, vein formation occurred throughout the uplift history of the metamorphic belt, representing long-continued fluid mobility. Thus numerous veins and generations of veins cross-cut earlier veins in a complex pattern of fluid pathways. Metallic mineralization commonly accompanies one or more of these vein generations (Kerrich and Fyfe 1981;McKeag and Craw 1989).In contrast to the above situation, portions of the Dalradian metamorphic belt of Scotland show only minor vein formation in the early and late stages of uplift. Instead, vein formation is concentrated into a relatively narrow part of the uplift history. This vein generation coincides with the formation of a set of struc...