Abstract:A supercritical solvent impregnation (SSI) technique was employed to incorporate, by batch- and semicontinuous-modes, bioactive olive leaf extract (OLE) into a food-grade multilayer polyethylene terephthalate/polypropylene (PET/PP) film for active food packaging applications. The inclusion of OLE in the polymer surfaces significantly modified the colour properties of the film. A correlation of 87.06% between the CIELAB colour parameters and the amount of the OLE impregnated in the film was obtained which sugge… Show more
“…Then, it would not even be surprising that in Chi-coated samples, higher condensation on the tight surface between the supporting polymer layer that is hydrophobic and the chitosan layer that is hydrophilic might lead to the higher mobility of water vapour molecules and, thus, faster permeation, as seen from higher WVTR values (Table 3). In contrast to the given results, others [53] found that PET/PP food-grade films impregnated with olive leaf extract had a lower WVP after the impregnation. Differences from the present study can be explained by the fact that the used substance was hydrophobic, contrarily to chitosan films that are hydrophilic.…”
This research was aimed to make biolayer coatings enriched with orange peel essential oil (OPEO) on synthetic laminate, oriented poly(ethylene-terephthalate)/polypropylene (PET-O/PP). Coating materials were taken from biobased and renewable waste sources, and the developed formulation was targeted for food packaging. The developed materials were characterized for their barrier (O2, CO2, and water vapour), optical (colour, opacity), surface (inventory of peaks by FTIR), and antimicrobial activity. Furthermore, the overall migration from a base layer (PET-O/PP) in an acetic acid (3% HAc) and ethanol aqueous solution (20% EtOH) were measured. The antimicrobial activity of chitosan (Chi)-coated films was assessed against Escherichia coli. Permeation of the uncoated samples (base layer, PET-O/PP) increased with the temperature increase (from 20 °C to 40 °C and 60 °C). Films with Chi-coatings were a better barrier to gases than the control (PET-O/PP) measured at 20 °C. The addition of 1% (w/v) OPEO to the Chi-coating layer showed a permeance decrease of 67% for CO2 and 48% for O2. The overall migrations from PET-O/PP in 3% HAc and 20% EtOH were 1.8 and 2.3 mg/dm2, respectively. Analysis of spectral bands did not indicate any surface structural changes after exposure to food simulants. Water vapour transmission rate values were increased for Chi-coated samples compared to the control. The total colour difference showed a slight colour change for all coated samples (ΔE > 2). No significant changes in light transmission at 600 nm for samples containing 1% and 2% OLEO were observed. The addition of 4% (w/v) OPEO was not enough to obtain a bacteriostatic effect, so future research is needed.
“…Then, it would not even be surprising that in Chi-coated samples, higher condensation on the tight surface between the supporting polymer layer that is hydrophobic and the chitosan layer that is hydrophilic might lead to the higher mobility of water vapour molecules and, thus, faster permeation, as seen from higher WVTR values (Table 3). In contrast to the given results, others [53] found that PET/PP food-grade films impregnated with olive leaf extract had a lower WVP after the impregnation. Differences from the present study can be explained by the fact that the used substance was hydrophobic, contrarily to chitosan films that are hydrophilic.…”
This research was aimed to make biolayer coatings enriched with orange peel essential oil (OPEO) on synthetic laminate, oriented poly(ethylene-terephthalate)/polypropylene (PET-O/PP). Coating materials were taken from biobased and renewable waste sources, and the developed formulation was targeted for food packaging. The developed materials were characterized for their barrier (O2, CO2, and water vapour), optical (colour, opacity), surface (inventory of peaks by FTIR), and antimicrobial activity. Furthermore, the overall migration from a base layer (PET-O/PP) in an acetic acid (3% HAc) and ethanol aqueous solution (20% EtOH) were measured. The antimicrobial activity of chitosan (Chi)-coated films was assessed against Escherichia coli. Permeation of the uncoated samples (base layer, PET-O/PP) increased with the temperature increase (from 20 °C to 40 °C and 60 °C). Films with Chi-coatings were a better barrier to gases than the control (PET-O/PP) measured at 20 °C. The addition of 1% (w/v) OPEO to the Chi-coating layer showed a permeance decrease of 67% for CO2 and 48% for O2. The overall migrations from PET-O/PP in 3% HAc and 20% EtOH were 1.8 and 2.3 mg/dm2, respectively. Analysis of spectral bands did not indicate any surface structural changes after exposure to food simulants. Water vapour transmission rate values were increased for Chi-coated samples compared to the control. The total colour difference showed a slight colour change for all coated samples (ΔE > 2). No significant changes in light transmission at 600 nm for samples containing 1% and 2% OLEO were observed. The addition of 4% (w/v) OPEO was not enough to obtain a bacteriostatic effect, so future research is needed.
“…And finally, the positive values of b* correlated with the yellow tones of the sample, while its negative values indicate the blue tones. Measurements were carried out using a portable spectrophotometer (CM-2600d, Konica Minolta Co., Osaka, Japan) following the method described by Cejudo et al [46]. In addition, in order to establish the total color difference between the functionalized films and their corresponding control samples, the ∆E index, calculated according to Equation (7):…”
Section: Optical Properties Of the Filmsmentioning
Active packaging is one of the currently thriving methods to preserve highly perishable foods. Nonetheless, the integration of active substances into the formulation of the packaging may alter their properties—particularly mass transfer properties—and therefore, the active compounds acting. Different formulations of chitosan (CH), starch (ST), and their blends (CH-ST), with the addition of mango leaf extract (MLE) have been polymerized by casting to evaluate their food preservation efficiency. A CH-ST blend with 3% MLE using 7.5 mL of the filmogenic solution proved to be the most effective formulation because of its high bioactivity (ca. 80% and 74% of inhibition growth of S. aureus and E. coli, respectively, and 40% antioxidant capacity). The formulation reduced the water solubility and water vapor permeability while increasing UV protection, properties that provide a better preservation of raspberry fruit after 13 days than the control. Moreover, a novel method of Headspace-Gas Chromatography-Ion Mobility Spectrometry to analyze the volatile profiles of the films is employed, to study the potential modification of the food in contact with the active film. These migrated compounds were shown to be closely related to both the mango extract additions and the film’s formulation themselves, showing different fingerprints depending on the film.
“…Poly(ethylene terephthalate) (PET) has remarkably stable physicochemical properties including excellent chemical resistance, great tensile strength, and high stability in a large temperature range. , PET has thus been used as an indispensable industrial material for a large variety of applications, including making packaging covers, containers, electronic devices, etc. − Specifically, PET is intensively used to produce textile fibers because of its excellent mechanical strength, wrinkle resistance, and excellent friction resistance. , Nevertheless, the high surface gloss of PET has made the fibers difficult to be applied into a larger context of usage. , A practical solution to modify the optical properties of PET fibers is to load nano-sized fillers with light-extinction property, such as TiO 2 nanoparticles, into the PET matrix. The method of particle loading can either be online addition, in which the masterbatches containing TiO 2 nanoparticles are melted and mixed with PET chips, followed by melt spinning to get the nanocomposite fiber (Figure ).…”
Titanium dioxide (TiO2) nanoparticles have
been extensively
used to modify the optical properties of various types of materials.
In particular, they have been intensively loaded onto polymer fibers
to quench the light reflection. In situ polymerization and online
addition are two common strategies for fabricating TiO2-loaded polymer nanocomposite fibers. The former does not require
separate preparation of masterbatches as the latter does and therefore
has its advantages in terms of decreasing the fabrication steps and
economic costs. Moreover, it has been found that in situ-polymerized
TiO2-loaded polymer nanocomposite fibers (e.g., TiO2/poly(ethylene terephthalate) fibers) usually have enhanced
light-extinction properties over those prepared by the online addition
process. Intuitively, there should be a difference in the filler particle
dispersion for the two fabrication processes. This hypothesis has
not yet been tackled due to the technical difficulty in acquiring
the three-dimensional (3D) filler morphology inside the fiber matrix.
In this paper, we report a study using the powerful focused ion beam-scanning
electron microscopy (FIB-SEM) with a resolution of 20 nm to directly
acquire the 3D microstructure of TiO2/poly(ethylene terephthalate)
nanocomposite (TiO2/PET) fibers. This microscopy technique
allows us to characterize the particle size statistics and the dispersion
inside TiO2/PET fibers. We have found that the particle
size of TiO2 inside the fiber matrix can be well modeled
by Weibull statistics. Surprisingly, we find that TiO2 nanoparticles
form more significant agglomeration in the in situ-polymerized TiO2/PET fibers. This observation is contrary to our common understanding
of the two fabrication processes. Namely, slightly altering the particle
dispersion with increased TiO2 filler size helps improve
the light-extinction properties. The slightly increased filler size
may have altered the Mie scattering between the nanoparticles and
the incident visible light, leading to enhanced light-extinction properties
of in situ-polymerized TiO2/PET nanocomposite fibers.
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