Abstract:b) Biomimetic inspired and durable bone implant in sheep based on nacre structures, nacre is marked as N in the radiograph [48] and optical microscope image. [49] Reproduced with permission. [48] Copyright 1999, Elsevier. Adapted with permission. [49] Copyright 2005, Elsevier. c) Nanosized bumps on the lotus leaf [25] and the curved fibrous microstructure of the silver ragwort leaf. [41] Adapted with permission. [25] Copyright 2011, Beilstein Institute for the Advancement of Chemical Sciences. Adapted with per… Show more
“…Inverse opal polymers are essentially porous materials, and the connected macropores are particularly suitable for the design and construction of micro-reactors due to the outstanding mass transfer. [21,192,262,263] The properties of inverse opal-derived SPCSs mainly depend on the chemical and physical properties of the polymer skeleton. They are generally films with good mechanical properties.…”
Low‐swelling polymers (LSPs) generally refer to materials with a low solvent absorption ratio or volume expansion rate at swelling equilibrium. LSPs with exceptional responsiveness could be upgraded to smart sensors with structural color self‐reporting by bridging photonic crystals (PCs). Based on the regulation of swelling to effective refractive index, lattice spacing, the order‐disorder arrangement of nanostructures, and incident/detection angle, the structural color feedback of smart photonic crystal sensors (SPCSs) can quantitatively and visually reveal the stimulus, which greatly promotes the interdisciplinary development of nanophotonic technology in the fields of chemical engineering, materials science, engineering mechanics, biomedicine, environmental engineering, etc. Herein, to clarify the role of the photonic structures and polymer molecules in high‐performance SPCSs, LSP‐based SPCSs are summarized and discussed, including general swelling mechanisms, color change strategies, structural design, and typical functional applications. It aims to figure out the combination rule between PC structures and LSPs, optimize the design of PC structures, and expound the corresponding structural color sensing mechanisms, inspiring the fabrication of next‐generation SPCSs. Finally, perspectives on future structural design and sensing applications are also presented. It is believed that SPCSs are multifunctional nanophotonic tools for the interdisciplinary development of numerous engineering fields in the future.
“…Inverse opal polymers are essentially porous materials, and the connected macropores are particularly suitable for the design and construction of micro-reactors due to the outstanding mass transfer. [21,192,262,263] The properties of inverse opal-derived SPCSs mainly depend on the chemical and physical properties of the polymer skeleton. They are generally films with good mechanical properties.…”
Low‐swelling polymers (LSPs) generally refer to materials with a low solvent absorption ratio or volume expansion rate at swelling equilibrium. LSPs with exceptional responsiveness could be upgraded to smart sensors with structural color self‐reporting by bridging photonic crystals (PCs). Based on the regulation of swelling to effective refractive index, lattice spacing, the order‐disorder arrangement of nanostructures, and incident/detection angle, the structural color feedback of smart photonic crystal sensors (SPCSs) can quantitatively and visually reveal the stimulus, which greatly promotes the interdisciplinary development of nanophotonic technology in the fields of chemical engineering, materials science, engineering mechanics, biomedicine, environmental engineering, etc. Herein, to clarify the role of the photonic structures and polymer molecules in high‐performance SPCSs, LSP‐based SPCSs are summarized and discussed, including general swelling mechanisms, color change strategies, structural design, and typical functional applications. It aims to figure out the combination rule between PC structures and LSPs, optimize the design of PC structures, and expound the corresponding structural color sensing mechanisms, inspiring the fabrication of next‐generation SPCSs. Finally, perspectives on future structural design and sensing applications are also presented. It is believed that SPCSs are multifunctional nanophotonic tools for the interdisciplinary development of numerous engineering fields in the future.
“…19,20 For a known photonic material, its optical structural color is related to the periodic nanoscale. 21 Therefore, they can have different structural colors as encoding elements by adjusting the size of the periodic nanostructure. PhCs possess excellent encoding stability since they do not suffer from photobleaching or fluorescence background interference.…”
Section: Introductionmentioning
confidence: 99%
“…A variety of coding technologies have been developed to expand the field of suspension barcodes, such as organic fluorescent, , quantum dot, graphic barcode, and photonic crystal (PhC) barcodes . PhCs are optical materials with the photonic band gap induced by periodic nanostructures. , For a known photonic material, its optical structural color is related to the periodic nanoscale . Therefore, they can have different structural colors as encoding elements by adjusting the size of the periodic nanostructure.…”
“…9,10 Extensive reviews of the characteristics which underpin these structures, and their applications are provided elsewhere. 11,12 In top-down fabrication methods where compounds are formed layer by layer, these graded thickness PhCs can be designed easily in 1D, 2D and 3D. [13][14][15] In this case, the thickness gradient is parallel to the growth direction that induces a graded refractive index contrast which shifts the position of the PBG.…”
The influence of thickness gradient and structural order on the spectral response of opal photonic crystals (PhCs) grown by evaporation-induced self-assembly (EISA) are presented. SEM imaging and angle resolved optical transmission spectroscopy are used to investigate the evolution of the PBG along a thickness gradient for opals grown from five different colloidal sphere concentrations at two different evaporation rates. The degradation of structural order along the thickness gradient is demonstrated, the occurrence of which attenuates the PBG with the thinning of the opal film and results in asymmetrical angle-resolved transmission spectra. The asymmetry in transmission intensity becomes more pronounced for opals grown from lower volume fractions, where secondary Bragg reflections also appear at low incident angles.
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