Structural batteries
(SBs) are a growing research subject worldwide.
The idea is to provide massless energy by using a multifunctional
material. This technology can provide a new pathway in electrification
and offer different design opportunities and significant weight savings
in vehicle applications. The type of SB discussed here is a multifunctional
material that can carry mechanical loads and simultaneously provide
an energy storage function. It is a composite material that utilizes
carbon fibers (CFs) as electrodes and structural reinforcement which
are embedded in a multifunctional polymer matrix (i.e., structural
battery electrolyte). A feasible composite manufacturing method still
needs to be developed to realize a full-cell SB. UV initiated polymerization
induced phase separation (PIPS) has previously been used to make bicontinuous
structural battery electrolytes (SBE) with good ionic conductivity
and mechanical performance. However, UV-curing cannot be used for
fabrication of a full-cell SB since a full-cell is made of multiple
layers of nontransparent CFs. The present paper investigates thermally
initiated PIPS to prepare a bicontinuous SBE and an SB half-cell.
In addition, the effect of curing temperature was examined with respect
to curing performance, morphology, ionic conductivity, and mechanical
and electrochemical performance. The study revealed that thermally
initiated PIPS provides a robust and scalable process route to fabricate
SBs. The results of this study are an important milestone in the development
of SB technology as they allow for the SB fabrication for an actual
application. However, other challenges still remain to be solved before
this technology can be introduced into an application.