“…The nano-crystallized GCs still possess high optical transmittance and the UC luminescence efficiency in GCs can be greatly enhanced, as compared to glass, when Ln 3+ ions are successfully incorporated into the crystal structures featuring lower probability of non-radiative transition ascribed to the lower phonon energy. So far, Yb 3+ -Tm 3+ co-doped GCs have been considered as significantly optical gain materials for UC NIR fiber lasers, noncontact optical thermometers, and bio-imaging [ 23 , 24 , 25 , 26 ]. Generally, Ln 3+ ions were expected to incorporate into the crystal structures via the ionic substitution for Y 3+ , La 3+ , Lu 3+ , Sc 3+ , and Sr 2+ in the GCs embedded with Na(Y/La/Lu)F 4 , LaF 3 , YF 3 , KSc 2 F 7 , and SrF 2 crystals, etc [ 27 , 28 , 29 , 30 , 31 ].…”