Manipulating the Coordination Structure of Molecular Cobalt Sites in Periodic Mesoporous Organosilica for CO2 Photoreduction
Raul Rojas-Luna,
Francisco J. Romero-Salguero,
Dolores Esquivel
et al.
Abstract:The catalytic activity towards CO2 photoreduction, including reaction rate, product selectivity, and longevity, is highly sensitive to the coordination structure of the catalytic active sites, and the precise design of the active site remains a challenge in heterogeneous catalysts. Herein, we report modulation of the coordination structure of MNx-type active sites (M = Co or Ni; x = 4 or 5) anchored on a periodic mesoporous organosilica (PMO) support to improve photocatalytic CO2 reduction. The PMO was functio… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.