“…Nevertheless, access to their magnetic states is enabled through their magnetically coupled valence electrons, either localized on the molecular ligand 8,9,13 or on the outer orbitals of the atoms. 12,14 Therefore, probing the electronic configuration and spin-polarization of the valence orbitals not only allows one to design molecular magnets with multiorbital spin configuration and accessible magnetic states 15,16 but also to rationalize the quantum level structure of surface-adsorbed atoms with open valence shells. 12 However, a direct measurement of the magnetic properties of the valence electrons for surface-adsorbed isolated atoms or molecules was still missing.…”