Manifestation of site energy landscapes for ion transport in borate glasses
Victor H. Gunawan,
Martin Schäfer,
Karl-Michael Weitzel
Abstract:The potential energy landscape of lithium borate glass of composition Li3B7O12 has been investigated by the charge attachment induced transport (CAIT) technique. Here, native Lithium ions have been replaced by...
“…As elaborated elsewhere, in this kind of unidirectional ion exchange, the effective diffusion coefficient for the foreign ion will always appear as concentration independent as long as D foreign ( D native,bulk . 32 This is a characteristic of the experiment. Since the goal of the experiment is to quantify only the native ion SED, no problem arises from this.…”
Section: Concentration Dependence Of Diffusion Coefficientsmentioning
The transport of native alkali ions in the energy landscape of alkali aluminum germanium phosphate (AAGP) glasses has been investigated by means of an alkali proton substitution (APS) experiment. This...
“…As elaborated elsewhere, in this kind of unidirectional ion exchange, the effective diffusion coefficient for the foreign ion will always appear as concentration independent as long as D foreign ( D native,bulk . 32 This is a characteristic of the experiment. Since the goal of the experiment is to quantify only the native ion SED, no problem arises from this.…”
Section: Concentration Dependence Of Diffusion Coefficientsmentioning
The transport of native alkali ions in the energy landscape of alkali aluminum germanium phosphate (AAGP) glasses has been investigated by means of an alkali proton substitution (APS) experiment. This...
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