Abstract:A convenient PNP pincer manganese catalyzed transfer hydrogenation of bromides to corresponding debrominated aryl compounds using ethanol as the hydrogen sources is reported. Importantly, the application of biomass-derived ethanol highlights the sustainability of the methodology. The use of 6phenyl substituted triazine-based P ipr N 5 P ipr manganese pincer catalyst allows for the debromination of various aryl bromides with good yields. Notably, the process also occurs with bromides derived from several classe… Show more
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