Managing Excess Lead Iodide with Functionalized Oxo‐Graphene Nanosheets for Stable Perovskite Solar Cells

Abstract

Stability issues could refrain from commercializing lead halide perovskite solar cells (PSCs) despite having comparable power conversion efficiency (PCE) to silicon solar cells. Overcoming drawbacks affecting their long‐term stability is gaining incremental importance. Excess lead iodide (PbI2) causes perovskite degradation, although it aids in crystal growth and defect passivation. Herein, we synthesized functionalized oxo‐graphene nanosheets (Dec‐oxoG NSs) to effectively manage the excess PbI2. Dec‐oxoG NSs provide anchoring sites to bind the excess PbI2 and passivate perovskite grain boundaries, thereby reducing charge recombination loss and significantly boosting the extraction of free electrons. The inclusion of Dec‐oxoG NSs leads to a PCE of 23.7% in inverted (p‐i‐n) PSCs. Devices retain 93.8% of their initial efficiency after 1,000 hours of tracking at maximum power points under continuous one‐sun illumination, and exhibit high stability under thermal and ambient conditions.

A novel radical-reaction interruption strategy for enhancing the light stability of perovskite solar cells

“…29 Recently, Li et al exploited a graphene derivative with rich hydroxyl, carbonyl, and carboxyl functional groups to manage the excess PbI 2 in perovskite films, achieving a 23.7% PCE with excellent operational stability. 30 Consequently, the excessive presence of PbI 2 poses a stability issue due to its propensity for photodecomposition, ultimately resulting in the collapse of the perovskite lattice under illumination. The current management strategies primarily focus on chemical elimination or conversion at the ground-state level to address the excess PbI 2 in perovskite films.…”