1999
DOI: 10.1002/(sici)1098-2787(1999)18:5<309::aid-mas2>3.3.co;2-c
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Maldi time‐of‐flight mass spectrometry of synthetic polymers
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Cited by 137 publications
(159 citation statements)
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“…The characteristics of this component are MW n = 3315, MW w = 3354, PDI = 1.01. The narrow molecular weight distribution for the copolymer fraction (polydispersity index <1.05) validates the approximation that the integrated intensity of the mass peak, calculated by integrating the peak area, was proportional to the mole fraction of the corresponding molecular ions (30) . This is crucial for the quantitative interpretation of the mass spectrum.…”
Section: Resultssupporting
confidence: 74%
“…The characteristics of this component are MW n = 3315, MW w = 3354, PDI = 1.01. The narrow molecular weight distribution for the copolymer fraction (polydispersity index <1.05) validates the approximation that the integrated intensity of the mass peak, calculated by integrating the peak area, was proportional to the mole fraction of the corresponding molecular ions (30) . This is crucial for the quantitative interpretation of the mass spectrum.…”
Section: Resultssupporting
confidence: 74%
“…Several applications demonstrating the use of this approach, which involves collecting fractions or depositing a sample on a prepared target before MALDI MS analysis [9], soon appeared in the literature. The SEC-MALDI MS combination seems to be particularly useful for analysis of rigid-rod synthetic polymers such as polyalkylthiophenes [30].…”
Section: Sec-maldi Mssupporting
confidence: 61%
“…With this technique many polymers were analyzed with different points of interest. [16] In the MALDI mass spectrum of the MEMO-modified nanoparticles, siloxane oligomers of more than 20 monomeric units were observed ( Figure 2). Each of the oligomers exhibits up to three mass signals.…”
Section: Grafting Of Silanes On Oxide Nanoparticlesmentioning
confidence: 59%
