Structural and magnetic characteristics of monodispersed Fe and oxide-coated Fe cluster assemblies Enhancement of magnetic coercivity and macroscopic quantum tunneling in monodispersed Co/CoO cluster assemblies Appl.Co-cluster-assembled films have been prepared using a size-controllable cluster beam deposition system, by which monodispersed Co clusters with a mean diameter, dϭ6 -13 nm are available. Their morphology and magnetic properties have been studied by scanning electron microscopy ͑SEM͒, small-angle x-ray scattering ͑SAXS͒ and magnetization measurements. The SEM images show that the film has a porous structure consisting of fine grains without a columnar texture and its density is about 25% of the bulk Co. The SAXS measurements indicate that monodispersivity of the incident clusters is maintained through their assembling process only for dϭ13 nm. All the specimens exhibit ferromagnetic behavior at room temperature and the magnetic coercive field H c rapidly increases with decreasing temperature: H c ϭ168 kA/m ͑2.1 kOe͒ at 5 K. Such an enhancement in H c is ascribed to the exchange anisotropy which arises from the antiferromagnetic Co-oxide layers covering the Co clusters, and to the assemblies of single-domain ferromagnetic clusters with the structure modification and magnetic interaction among them. The monotonic increase in H c at 300 K with increasing d is simply understood in terms of the single-domain particle theory.