“…The iron cations are all ferric, and are are located in octahedral 12k, 4f 2 and 2a sites, and tetrahedral 4f 1 sites, in addition to a trigonal bipyramidal 2b site which is understood to be mainly responsible for the c-axis magnetic anisotropy [8], but which has not been well characterized optically. In fact, although optical and magnetooptical spectra of BaFe 12 O 19 have been examined previously in the spectral region extending from the visible to the near infra-red [5,6,9,10], no attempt has been made, to our knowledge, to examine the low-temperature spectral detail in terms of possible assignments of crystal-field transitions to the above optical centres. This paper attempts to rectify this situation by presenting, for the first time, the low-temperature Faraday rotation spectra of BaFe 12 O 19 between 1.5 eV and 2.4 eV, and suggesting assignments of the spectral detail to crystal-field transitions originating from the various Fe 3+ sites.…”