Magnetocaloric properties in (La,R)(Fe,Mn,Si)₁₃H (R = Ce and Pr)—toward a better alloy design that results in a reduction in volume of permanent magnets and the establishment of long-term reliability in cooling systems

Abstract

The magnetocaloric effect (MCE) in La1−z R z (Fe0.89−x Mn x Si0.11)13H y max (R = Ce and Pr) is verified in view of correlation between alloying recipes such as selection of doping elements and fundamental physics that governs MCE. The Ce-doped specimen with z = 0.3 & x = 0.017 exhibits a peaky isothermal entropy change ΔS M profile with a maximum value of 20 J kg−1 K under a field change of 0.8 T at the Curie temperature of 285 K. In contrast, the enlarged field dependence of the Curie temperature and diminished hysteresis results in the adiabatic temperature change ΔT ad of 2.7 K under a field change of 0.8 T at the Curie temperature of 289 K for the Pr-doped specimen.