Magneto-structural correlation in dimeric copper(II) benzoates

Thermal stability and electrochemical behaviour of Tetrakis-μ-benzoatodicopper(II)

“…for Cu 2 (C 6 H 5 COO) 4 A beautiful, blue block of CuB crystals was grown from a reaction mixture of the complex with acetophenone and benzaldehyde by refluxing for 8 hours and leaving to cool slowly to room temperature. Single crystal X-ray analysis of the crystal revealed a paddle-wheel structure of a complex with benzoic acid at the axial positions, similar with that reported by Ohba et al [22]. …”

Ternary Copper(II) Complexes With Indomethacin, a Potent Non-Steroidal Antiinflammatory Drug. Crystal Structure of Bis (Dimethylformamide)-Tetrakis[1-(4-Chlorobenzoyl)-5-Methoxy-2-Methyl-1-H-Indole-3-Acetato]Dicopper(II). Antiinflammatory Properties and Prevention of Gastrointestinal Side Effects by Nanocapsules

“…This enzyme released by inflammation cells and particularly polymorphonuclear cells is generally considered as a good marker of inflammatory process and classically measured to appreciate such a phenomenon. Since myeloperoxidase-mimetic activity has been reported with some copper complexes [12][13][14][15][16][17][18][19][20][21][22][23][24][25] (1) 2.629 (2) O (22) [12,27]. In a previous study, we showed that high doses of copper indomethacinate exerted a slight protective effect on the gastrointestinal tract [16].…”

“…This disease is characterized by abnormal accumulation of amyloid peptide (1 A4) from its precursor amyloid precursor protein. Mutations in the gene encoding amyloid precursor on chromosome 21 have been found to segregate with AD [2]. The inflammatory hypothesis of Alzheimer' s disease is based on the observation that individuals susceptible to the disease and who are undergoing treatment for a known inflammatory injury will be inadvertently treating their latent AD and will therefore have a reduced risk of developing a clinical case [3][4].…”

Formation of Chiral Solids via a Molecular Building Block Approach

“…The metallacrown separation through the copper dimer bridge is 7.13 A > , with symmetrical Cu }O distances (2.24 A > ). The Cu}Cu distance between atoms of the paddlewheel dimer is 2.65 A > which is essentially the same as other molecules of this class that have axial substituents (20). The two chain directors (face-to-face and edge-to-edge) are oriented at 98. lacrown/copper benzoates is 16.32 A > (Cu }Cu ) below the one that is shown.…”