Magnetism and transport studies in off-stoichiometric metallic perovskite compounds GdPd3Bx (x=0.25, 0.50 and 0.75)

Synthesis, microstructure, and mechanical properties of YPd3B thin films

“…The ternary perovskite boride YPd 3 B belongs to a large group of cubic non-oxide perovskite phases with the general formula of RM 3 X (space group Pm3m), where R and M are metals, and X is a light element of B, C, or N. These phases are drawing a lot of attention due to their interesting properties [1][2][3][4][5][6][7][8][9][10][11][12][13] such as superconductivity [1][2][3], negative thermal expansion [4], giant magnetoresistance [5], and negative temperature coefficient of resistance [6]. For the mechanical properties, it has been suggested that RM 3 X may possess an unusual combination of metallic and ceramic properties similar to damage tolerant nanolaminate compounds, the so-called MAX-phases [7][8][9][10].…”

ThPt3+xBe (x= 0.08): Crystal Structure and Physical Properties

“…A typical example of such a system is EuPd 3 B x , in which the inclusion of additional boron induces valence instability of Eu and thus transition from non‐magnetic (Eu 3+ ) to magnetic (Eu 2+ ) state, An antiperovskite‐like EuPd 3 B x structure appears after filling the octahedral void in binary compound EuPd 3 (crystallizing with AuCu 3 type) with a B atom. Such observations are rather common and have been discussed in the literature , …”