Magnetically recoverable ferromagnetic 3D hierarchical core-shell Fe3O4@NiO/Co3O4 microspheres as an efficient and ligand-free catalyst for C–S bond formation in poly (ethylene glycol)

A highly-efficient method for the synthesis of S-aryl dithiocarbamates was reported. By using tetramethylthiuram monosulfide (TMTM) and aryl boronic acids as starting materials, the C(sp2)-S bond formation reaction proceeded smoothly, giving the desired aryl dithiocarbamates in good to excellent yields. The methodology features easy performance, broad functional group tolerance, and excellent yields, showing potential synthetic value for the preparation of a diversity of biologically or pharmaceutically active compounds.

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Magnetically recoverable ferromagnetic 3D hierarchical core-shell Fe₃O₄@NiO/Co₃O₄ microspheres as an efficient and ligand-free catalyst for C–S bond formation in poly (ethylene glycol)

Cited by 4 publications

References 40 publications

In situ synthesis of bimetallic γ-Fe2O3/Cu nanoparticles over pectin hydrogel obtained from biomass resource (orange peel) as a reusable green catalyst for oxidation and C-S cross-coupling reactions

In situ synthesis of bimetallic γ-Fe2O3/Cu nanoparticles over pectin hydrogel obtained from biomass resource (orange peel) as a reusable green catalyst for oxidation and C-S cross-coupling reactions

One-pot thermo-induced radical-radical oxidative cross-coupling for symmetrical dimeric thiadiazole monosulfide formation

Synthesis of Aryl Dithiocarbamates from Tetramethylthiuram Monosulfide (TMTM) and Aryl Boronic Acids: Copper-Catalyzed Construction of C(sp2)–S Bonds

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