Abstract:With a view to fabricating a new remote input‐output system by applying functional ionic liquid crystalline (ILC) materials, we have developed novel ILC compounds containing a nitroxide radical unit in the organic cations, which show an enantiotropic smectic A (SmA) phase. We have implemented the magnetic manipulation of a droplet of one of the ILC compounds on the basis of the intermolecular magnetic interactions between radical moieties. This ILC monoradical compound shows a 55 % larger increase in paramagne… Show more
A newly synthesised liquid crystalline nitroxide radical with a terminal trifluoromethyl group exhibits a cybotactic nematic phase. EPR spectroscopy of the spin-labelled LC implies that molecules move into and out of the cybotactic clusters.
A newly synthesised liquid crystalline nitroxide radical with a terminal trifluoromethyl group exhibits a cybotactic nematic phase. EPR spectroscopy of the spin-labelled LC implies that molecules move into and out of the cybotactic clusters.
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