Cross sections for electronic excitation and de-excitation among the ground state and lowest-lying seven electronic excited states of carbon monoxide (CO) by low-energy electron-impact are computed using R-matrix method. The excitation cross sections from the ground state to the electronic states a
3Π, a'3Σ+ and A
1Π agree with previously experimental and theoretical results. Additionally, the cross sections for I
1Σ- and D
1Δ states of CO which will cascade to CO a'3Σ+ and A
1Π states are calculated. What’s more, in contrast to the typical increase in electronic excitation cross sections with collision energy, the de-excitation cross sections show a negative trend with increasing energy.