Magnetic Susceptibilities and Electron Paramagnetic Resonance Spectra of Lithium-Rich Lanthanide Oxides Li8Pro6and Li8TbO6

Hinatsu, Yukio

doi:10.1006/jssc.1996.7193

Journal of Solid State Chemistry

1997

DOI: 10.1006/jssc.1996.7193

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Magnetic Susceptibilities and Electron Paramagnetic Resonance Spectra of Lithium-Rich Lanthanide Oxides Li8Pro6and Li8TbO6

Yukio Hinatsu¹

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Cited by 3 publications

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A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

Boggiano,

Chowdhury,

Roy

et al. 2024

Angewandte Chemie

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The imidophosphorane ligand, [NPtBu3]– (tBu = tert‐butyl), enables isolation of a pseudo‐tetrahedral, tetravalent praseodymium complex, [Pr4+(NPtBu3)4] (1‐Pr), which is characterized by a suite of physical characterization methods including single‐crystal X‐ray diffraction, electron paramagnetic resonance, and L3‐edge X‐ray near‐edge spectroscopies. Variable‐temperature direct‐current magnetic susceptibility data, supported by multiconfigurational quantum chemical calculations, demonstrate that the electronic structure diverges from the isoelectronic Ce3+ analogue, driven by increased crystal field. The four‐coordinate environment around Pr4+ in 1‐Pr, which is unparalleled in reported extended solid systems, provides a unique opportunity to study the interplay between crystal field splitting and spin‐orbit coupling in a molecular tetravalent lanthanide within a pseudo‐tetrahedral coordination geometry.

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A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

Boggiano,

Chowdhury,

Roy

et al. 2024

Angewandte Chemie

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A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

Boggiano,

Chowdhury,

Roy

et al. 2024

Angew Chem Int Ed

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The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

et al. 2020

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Magnetic Susceptibilities and Electron Paramagnetic Resonance Spectra of Lithium-Rich Lanthanide Oxides Li8Pro6and Li8TbO6

Cited by 3 publications

References 17 publications

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

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Magnetic Susceptibilities and Electron Paramagnetic Resonance Spectra of Lithium-Rich Lanthanide Oxides Li8Pro6and Li8TbO6

Cited by 3 publications

References 17 publications

A Four‐Coordinate Pr4+ Imidophosphorane Complex

A Four‐Coordinate Pr4+ Imidophosphorane Complex

A Four‐Coordinate Pr4+ Imidophosphorane Complex

The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

Contact Info

Product

Resources

About

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex

A Four‐Coordinate Pr⁴⁺ Imidophosphorane Complex