“…A FM nanoparticle is defined as superparamagnetic (SPM), when the energy barrier, E B , for a magnetization reversal is comparable to the thermal energy, k B T, during the measurement. The direction of the superspin then fluctuates with a frequency f or a characteristic relaxation time, τ −1 = 2π f. It is given by the Néel-Brown expression [3], τ = τ 0 exp(KV / k B T ), (1) where τ 0 ∼ 10 −10 s is the inverse attempt frequency, K an effective anisotropy constant and V the volume of the nanoparticle. The energy barrier is here approximated by E B = KV.…”