“…This is due to the large positive heat of mixing, which is 42 kJ/mol in the solid state at equiatomic composition and 28 kJ/mol in liquid state [7]. Though this system has been prepared by a few methods such as magnetron sputtering, pulsed laser deposition, vapour quenching, sol-gel method, molecular beam epitoxy, etc., and its properties investigated [8][9][10][11][12], reports on its electrodeposition are scarce. The stability of electrodeposited Ag-Fe alloy has been reported by Roy et al [13].…”