Magnetic properties of Gd@C82 metallofullerene

Cluster-size dependent internal dynamics and magnetic anisotropy of Ho ions in HoM2N@C80and Ho2MN@C80families (M = Sc, Lu, Y)

“…[6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] Recent discovery of single molecular magnetic behaviour in the Dy x Sc 3Àx N@C 80 -I h (x ¼ 1-3) series 12,19 calls for more detailed studies of NCF encapsulating lanthanide ions with large magnetic anisotropy.…”

Magnetic Properties and Crystal Structure of Solvent‐Free Sc@C82 Metallofullerene Microcrystals

“…[23,35] Recently, ESR measurements of some lanthanide metallofullerenes have been reported. [39][40][41][42] Temperature dependence of the physical properties of such metallofullerene solids or single crystals has been also characterized by ESR, SQUID magnetic measurements [43][44][45][46][47][48][49][50] and X-ray diffraction measurements. [51,52] Antiferromagnetic-like interactions have been observed for powder crystals of La@C 82 , [44] Gd@C 82 [43,44] and heavy rare-earth monometallofullerenes [48] by the SQUID magnetic measurements.…”

Enrichment and Characterization of a Noble Gas Fullerene: Ar@C60

“…[4][5][6][7] The isolation of milligram quantities of the metal endohedral fullerenes has permitted the study of many unique properties of these species. Rare-gas endohedral fullerenes were first observed 8 in collisions between fast fullerene cations and stationary rare-gas atoms leading to rare-gas C n cations.…”