Magnetic Properties of Fe, Co and Ni Based Nanopowders Produced by Chemical-Metallurgy Method

Abstract

This research study describes the magnetic properties of Fe, Co and Ni metallic nanopowders (NPs) and their ternary nanocomposites (NCs), which can be used as fillers in radio-wave absorbing composite materials and coatings, as well as for magnetic protection of banknotes and security paper. The nanopowders were prepared by the chemical metallurgy method. The desired properties of Fe, Co and Ni NPs and NCs were achieved by co-precipitation, the addition of surfactants and changes in reduction temperature and time parameters. Magnetic measurements showed that all samples of pure metal NPs are semi-hard magnetic materials. The added surfactants have distinct effects on the dimensional and magnetic characteristics of Fe, Co and Ni NPs. Ni–Co–Fe NCs are also mainly semi-hard magnetic materials. Fine-tuning of their composition and chemical reduction temperatures allows controlling the values of Ms and Hc in large ranges from 49 to 197 A·m2/kg and from 4.7 to 60.6 kA/m, respectively.