2021
DOI: 10.3390/ma14195873
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Magnetic Properties and Morphology Copper-Substituted Barium Hexaferrites from Sol-Gel Auto-Combustion Synthesis

Abstract: The copper (Cu) substitution in barium hexaferrite (BaFe12O19) crystals from the sol-gel auto-combustion synthesis is demonstrated as a cost-effective pathway to achieve alterable magnetic properties. Subsequent heat treatments at 450 °C and 1050 °C result in irregularly shaped nanoparticles characterized as the M-type BaFe12O19 with the secondary phase of hematite (α-Fe2O3). Despite the mixed phase, the substantial coercivity of 2626 Oe and magnetization as high as 74.8 emu/g are obtained in this undoped ferr… Show more

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Cited by 13 publications
(8 citation statements)
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References 30 publications
(72 reference statements)
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“…[60,[118][119][120][121]. They are also developing new synthesis methods, such as sol-gel processing and electrospinning, [122][123][124] to create materials with specific structures and properties.…”
Section: Design and Synthesis Of New Materialsmentioning
confidence: 99%
“…[60,[118][119][120][121]. They are also developing new synthesis methods, such as sol-gel processing and electrospinning, [122][123][124] to create materials with specific structures and properties.…”
Section: Design and Synthesis Of New Materialsmentioning
confidence: 99%
“…This may avoid precipitation of crystalline metal oxides and metal hydroxides. [40] Further, thermal decomposition of metal-polymeric complex results in the formation of silver nanoparticles, in which organic part in the complex act as the reducing agent.…”
Section: Introductionmentioning
confidence: 99%
“…In addition, under hot conditions polymerization reaction between citric acid and polyols from fruit extract can take place, while metal ions are stuck in this structure. This may avoid precipitation of crystalline metal oxides and metal hydroxides [40] . Further, thermal decomposition of metal‐ polymeric complex results in the formation of silver nanoparticles, in which organic part in the complex act as the reducing agent.…”
Section: Introductionmentioning
confidence: 99%
“…On the other hand, hexaferrites have a sufficiently high crystallographic texture that permits the exploitation of their magnetocrystalline anisotropy fields, H a , affording them the potential for miniaturization and improved integration of microwave and millimeter-wave (MMW) devices. Specifically, Mtype Ba-hexaferrites (i.e., BaFe 12 O 19 , BaM) have attracted much attention for applications in monolithic-microwave-integrated circuits (MMIC) due to their strong and adjustable H a , that acts as an effective internal field [4][5][6][7].…”
Section: Introductionmentioning
confidence: 99%
“…4 Oe/GHz. ∆H a and ∆H p relate to the crystalline anisotropy and porosity-induced linewidth-broadening contributions.…”
mentioning
confidence: 99%