Spectra of the magneto-optical Kerr effect, in a series of ͓Fe (xML͒/Au (xML)͔ N superlattices with integer and noninteger values of x (1рxр15), were measured. For xϭ1 the superlattic forms an L1 0 -type ordered alloy structure. The magneto-optical spectrum of the superlattice exhibits a prominent structure around 4 eV, which shows a systematic shift toward higher energies as x increases (1рxр5). No such structure can be reproduced by an optical calculation assuming a simple stack of thin Fe and Au layers. Ab initio band calculations have shown similar magneto-optical spectra and a similar peak shift with an increase in x (1рxр6). This suggests that electronic structures which differ from that of a simple stack of thin Fe and Au are realized in the superlattices. For noninteger values of x, oscillatory behavior with a period of one monolayer was observed in the low energy region of the magneto-optical spectra.