2001
DOI: 10.1016/s0009-2614(01)00695-9
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Magnetic field effects on TMPD cation–electron recombination fluorescence in saturated hydrocarbons

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Cited by 2 publications
(1 citation statement)
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“…A MARY spectrum is essentially a conventional stationary magnetic field effect (MFE) curve, the dependence of the yield of recombination fluorescence from radical ion pairs in irradiated solutions on extemal static magnetic field, with sharp lines in zero and low field due to the degeneracy of the spin energy levels of ttle pair. Similar techniques have also been implemented by other groups [9][10][11][12][13][14][15]. To amplify the weak and narrow MARY lines against the slowly changing background of the MFE, magnetic field modulation with lock-in detection of the signal and symmetric passage through zero of the field is used, producing a first-derivative experimental spectrum resembling CW ESR lines.…”
Section: Methodsmentioning
confidence: 99%
“…A MARY spectrum is essentially a conventional stationary magnetic field effect (MFE) curve, the dependence of the yield of recombination fluorescence from radical ion pairs in irradiated solutions on extemal static magnetic field, with sharp lines in zero and low field due to the degeneracy of the spin energy levels of ttle pair. Similar techniques have also been implemented by other groups [9][10][11][12][13][14][15]. To amplify the weak and narrow MARY lines against the slowly changing background of the MFE, magnetic field modulation with lock-in detection of the signal and symmetric passage through zero of the field is used, producing a first-derivative experimental spectrum resembling CW ESR lines.…”
Section: Methodsmentioning
confidence: 99%