Densification, grain growth, magnetic and dielectric properties of sintered Li–Zn ferrite (Li0.3Zn0.4Fe2.3O4) doped with nano silicon dioxide (10 nm) were investigated. The density and microstructural results revealed that increasing the nano-SiO2 content resulted in lower density and higher porosity at sintering temperatures below 1 000 °C, whereas at higher temperatures, this led to higher density and grain growth. In addition, nano-SiO2 content greater than 2 wt.% resulted in more reduction in porosity and had no effect on grain growth. Moreover, the highest density and the maximum induction (Bs = 380 mT) were obtained for the sample containing 2 wt.% nano-SiO2 and sintered at 1 100 °C for 1.5 h, in comparison with undoped samples. Furthermore, the variation of magneto-dielectric properties as a function of frequency were explained according to Koop's theory and electron hopping between the Fe+ 2 and Fe+ 3 ions.