Magnesium hydrazinidoborane: Synthesis, characterization and features for solid-state hydrogen storage

Castilla-Martinez, Carlos A.; Roussignol, Lucas; Demirci, Umit B.

doi:10.1016/j.ijhydene.2021.07.169

Cited by 7 publications

(3 citation statements)

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“…% H 2 ) and calcium hydrazinidoborane (Ca(HB) 2 , Ca(N 2 H 3 BH 3 ) 2 , 9.3 wt. % H 2 ) was finally reported [316,317]. In the case of Ca(HB) 2 , a mixture of HB and CaH 2 has to be ball-milled.…”

Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

“…% H2) and calcium hydrazinidoborane 9.3 wt. % H2) was finally reported [316,317]. In the case of Ca(H CaH2 has to be ball-milled.…”

Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

“…Then, a particular heat treatment has t the HB/CaH2 mixture at 62 °C for 50 min; after this, the mixture rapidly to room temperature. Ca(HB)2 forms around 60 °C, the t melts, and the reaction takes place between the solid CaH2 and nately, the obtained product was composed of 71% Ca(HB)2 and crystalline compound with a monoclinic unit cell (Ic s. Mg(HB) 2 was prepared using a solvent-based approach [317]. Di-n-butylmagnesium was used as the Mg precursor, and it was added dropwise into a HB solution in THF.…”

Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

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Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

et al. 2021

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Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen storage materials in the solid-state. Thus, different strategies have been developed to improve the dehydrogenation properties of these materials. The purpose of this review is to provide an overview of recent advances (for the period 2015–2021) in the destabilization strategies that have been considered for selected boron-based compounds. With this aim, we selected seven of the most investigated boron-based compounds for hydrogen storage applications: lithium borohydride, sodium borohydride, magnesium borohydride, calcium borohydride, ammonia borane, hydrazine borane and hydrazine bisborane. The destabilization strategies include the use of additives, the chemical modification and the nanosizing of these compounds. These approaches were analyzed for each one of the selected boron-based compounds and these are discussed in the present review.

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Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

“…% H2) and calcium hydrazinidoborane 9.3 wt. % H2) was finally reported [316,317]. In the case of Ca(H CaH2 has to be ball-milled.…”

Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

Section: Alkaline Earth Hydrazinidoboranesmentioning

confidence: 99%

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