A method has been developed for the determination of cobalt in atmospheric dust samples and applied to the analysis of environmental samples from the cemented tungsten carbide industry. The sample is fused with potassium peroxydisulfate after preliminary ignition of any free carbon present; the cooled melt is dissolved in water, acidified, and diluted to volume; after thorough mixing, a suitable aliquot portion is removed, filtered, washed, evaporated almost to dryness, oxidized with concentrated nitric acid, and evaporated to dryness; after solution in water and hydrochloric acid, the cobalt is determined colorimetrically by means of a modification of the nitroso R salt method. The application of this method to atmospheric carbide dust samples has indicated that for samples containing 0.1 mg. of cobalt or more, its accuracy is at least 95%. ANALYTICAL methods for the determination of cobalt l.have been developed for application to such materials as ores, minerals, special steels, alloys and other metallurgical products, enamels, driers, soils, pasture samples, and biological