Abstract:Dedicated to Professor Cameron Jones on the occasion of his 60th birthday.react with iodoarenes in oxidative addition reactions. With iodobenzene, magnesium phenyl and magnesium iodide complex fragments were obtained, and from a reaction with 4-iodo-1,2,3,5-tetramethylpyrazolium iodide, [ Me PZI]I, the pyrazol-4-ylidene complex [( Dip nacnac)MgI( Me PZ)] was structurally characterised, alongside other products. The isomeric imidazol-2-ylidene complex [( Dip nacnac)MgI( Me NHC)], where Me NHC is 1,3,4,5-tetrame… Show more
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