Abstract. The assemblage titanian clinohumite + forsterite + spinet + calcite is widespread in marbles from the eastern Bergell contact aureole (Switzerland/Italy). The Bergell titanian clinohumites vary considerably in composition (Ti0 2 : 0.19 to 2.05 wt%, F: 2.2 to 3.4 wt%). Electron microprobe analyses show that the titanian clinohumites contam less than detectable amounts of Co, Cu, Ni, Zn, Al, Cr and CI. No trace of ferric iron could be detected by Moessbauer spectroscopy. Moreover, the Moessbauer spectra indicate that Fe 2 + occurs only in one of the five octahedral positions in the crystal structure of the studied titanian clinohumite. Under the conditions of the contact metamorphism (600 650° C, 3 kb total pressure) the compositional variation along the exchange vector TiO 2 M 1 (OH,F) 2 takes place at constant x 0 , 1 which is fixed by the pore fluid. Titanian clinohumite sometimes contains geikielite inclusions which strongly fractionate Fe and Mn relative to titanian clinohumite. The geikielites from the Bergell marbles are poor in Cr 2 0 3 , Fe 2 0 3 and MnO, and thus different from those found in carbonatites, kimberlites and serpentinized ultramafic rocks.