Maghemite Intercalated Montmorillonite as New Nanofillers for Photopolymers

Tarablsi, Bassam; Delaite, Christelle; Brendlé, Jocelyne; Croutxé‐Barghorn, Céline

doi:10.3390/nano2040413

Cited by 8 publications

(12 citation statements)

References 44 publications

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“…MMT nanoparticles have been found to decrease coating gloss in some studies. This decline is supposed to be due to the surface roughness created by MMT particles . On the other hand, there are many studies in literature showing that MMT additives increased gloss of polymer films .…”

Section: Resultsmentioning

confidence: 99%

Synthesis of poly(butyl acrylate‐co‐methyl methacrylate)/montmorillonite waterborne nanocomposite via semibatch emulsion polymerization

Vatansever

İnan

Doǧan

et al. 2015

J of Applied Polymer Sci

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Poly(butyl acrylate-co-methyl methacrylate)-montmorillonite (MMT) waterborne nanocomposites were successfully synthesized by semibatch emulsion polymerization. The syntheses of the nanocomposites were performed in presence of sodium montmorillonite (Na-MMT) and organically modified montmorillonite (O-MMT). O-MMT was used directly after the modification of Na-MMT with dimethyl dioctadecyl ammonium chloride. Both Na-MMT and O-MMT were sonified to obtain nanocomposites with 47 wt % solids and 3 wt % Na-MMT or O-MMT content. Average particle sizes of Na-MMT nanocomposites were measured as 110-150 nm while O-MMT nanocomposites were measured as 200-350 nm. Both Na-MMT and O-MMT increased thermal, mechanical, and barrier properties (water vapor and oxygen permeability) of the pristine copolymer explicitly. X-ray diffraction and transmission electron microscope studies show that exfoliated morphology was obtained. The gloss values of O-MMT nanocomposites were found to be higher than that of the pristine copolymer.

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Section: Resultsmentioning

confidence: 99%

Synthesis of poly(butyl acrylate‐co‐methyl methacrylate)/montmorillonite waterborne nanocomposite via semibatch emulsion polymerization

Vatansever

İnan

Doǧan

et al. 2015

J of Applied Polymer Sci

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“…Согласно исследованиям, прочность при сжатии компактной костной ткани 100-230 МПа, губчатой около 10 МПа. Отсутствие токсического действия на организм соединений, использующихся в составе керамики, подтверждены исследованиями [15][16][17][18]. Это позволяет считать материал, полученный в ходе работ, нетоксичным.…”

Section: Ek Papynov Chairman Of the Far Eastern Section Of The Scient...unclassified

“…В качестве связующего используются силикатные материалы или органические соединения [14]. Органические связующие по сравнению с силикатными обладают меньшей радиационной стойкостью и в условиях космического пространства подвергаются частичной деструкции, сопровождающейся газовыделением [15,16].…”

Section: формирование покрытий на силикатной основе содержащих воллас...unclassified

“…К наиболее масштабным сферам применения волластонита относится производство различных видов керамики, в том числе биомедицинского назначения [3][4][5][6][7][8], строительных материалов [9][10][11][12][13][14], бумаги, красок, лаков, защитных покрытий [15][16][17][18][19][20][21]. Растет доля использования волластонита в технологии получения полимерных композиционных материалов [22][23][24][25][26].…”

Section: глава 3 синтез волластонита и функциональных материалов на е...unclassified

See 1 more Smart Citation

Функциональные Керамические И Композитные Материалы Практического Назначения: Синтез, Свойства, Применение

2022

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Монография подготовлена коллективом авторов Дальневосточной секции Научного совета РАН по керамическим материалам совместно с коллегами из других регионов РФ, а также из Беларуси, Армении. Книга посвящена современным достижениям в области разработки физико-химических основ создания функциональных керамических и композиционных материалов. Представлены результаты исследований по актуальным научным направлениям в области создания и исследования керамических, полимерных, цементных, магнитных материалов и покрытий различного практического назначения.

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“…Tarablsi et al utilized maghemite intercalated MMT at 1 and 2 wt% loadings in photopolymerized difunctional acrylates [88]. The team noted that polymer nanocomposites are usually prepared by in situ polymerization, sol-gel processing, or melt-compounding.…”

Section: Years 2010-2014: Interface Chemistry Of Smpincs Leads To Enhmentioning

confidence: 99%

Shape Memory Polymer–Inorganic Hybrid Nanocomposites

Reit

Lund

Voit

2014

Organic-Inorganic Hybrid Nanomaterials

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Shape memory polymers (SMPs) have been the focus of much research over the last few decades. From the novelty of temporarily fixing a threedimensional shape from a planar polymer sheet, to the uses that SMPs are seeing today as softening biomedical implants and self-deploying hinges, this class of smart materials has successfully been used to tackle a variety of biological, electrical, and mechanical problems. However, the properties of these networks are limited by the organic nature of the SMPs. To enhance their properties, researchers across the globe have looked into imparting the desirable properties of inorganic composite materials to these polymer networks. As the field of shape memory polymer composites began to grow, researchers quantified the unique enhancements that came at varying filler loading levels as a result of controlled material interface interactions. Specifically, the incorporation of nanofillers of various shapes and sizes leads to increased internal interfacial area relative to micro-and macrocomposites at identical loading fractions and imparts interesting mechanical, optical, electrical, thermal, and magnetic properties to these emerging nanocomposites. This new class of material, referred to in this review as shape memory polymer-inorganic nanocomposites (SMPINCs), allows a host of new interactions between the smart polymer and its surrounding environment as a result of the ability to control the internal environment of the polymer network and nanofiller. In this work, the reader is introduced to both the methods of preparing these composites and the effects the fillers have on the biological, electromagnetic, and mechanical properties of the resulting composite.

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Maghemite Intercalated Montmorillonite as New Nanofillers for Photopolymers

Cited by 8 publications

References 44 publications

Synthesis of poly(butyl acrylate‐co‐methyl methacrylate)/montmorillonite waterborne nanocomposite via semibatch emulsion polymerization

Synthesis of poly(butyl acrylate‐co‐methyl methacrylate)/montmorillonite waterborne nanocomposite via semibatch emulsion polymerization

Функциональные Керамические И Композитные Материалы Практического Назначения: Синтез, Свойства, Применение

Shape Memory Polymer–Inorganic Hybrid Nanocomposites

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