Nuclear Magnetic Resonance Spectroscopy 1988
DOI: 10.1016/b978-0-08-091699-6.50012-x
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Macromolecules

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Cited by 36 publications
(45 citation statements)
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“…This peak increase is consistent with MA weight percentage, so the MA grafting level was measured from the intensity of 1780 cm À1 , and the thickness variation of each sample was corrected by 2019 cm À1 intensity for internal reference peak. 24 Figure 3 shows the peak ratio of 1780/2019 cm À1 as a function of PE-g-MA content. MA weight percentages calculated by peak ratio are summarized in Table I.…”
Section: Resultsmentioning
confidence: 99%
“…This peak increase is consistent with MA weight percentage, so the MA grafting level was measured from the intensity of 1780 cm À1 , and the thickness variation of each sample was corrected by 2019 cm À1 intensity for internal reference peak. 24 Figure 3 shows the peak ratio of 1780/2019 cm À1 as a function of PE-g-MA content. MA weight percentages calculated by peak ratio are summarized in Table I.…”
Section: Resultsmentioning
confidence: 99%
“…The peak at 3.60 ppm corresponds to the methylester-group found in PMMA [37]. The peaks in the region between δ = 2.2 ppm and 1.3 ppm are significant for the CH 2 -group [38].…”
Section: Resultsmentioning
confidence: 99%
“…The sum of their integral intensity equals that of the peak at δ = 3.60 ppm. The peaks in the region between δ = 2.2 ppm and 1.3 ppm are significant for the CH 2 -group [37]. Differences between the bulk and capillary bridge samples occur in this δ-range, which are presumably due to impurities inferred from the preparation of the capillary suspension.…”
Section: Figmentioning
confidence: 99%
“…The use of MRS is limited to these and several other nuclei, based on their physical properties, that is, possessing a resonance frequency that responds, or aligns, within a magnetic field, and the release of energy after perturbation following application of an RF pulse, all of which make these nuclei MR visible. For a given nucleus (e.g., 1 H), chemically distinct groups within a molecule that contain the given nucleus possess minor differences in their local resonant frequencies owing to the inhomogeneous and unique distribution of electrons within the molecule (Bovey, Jelinski, & Mirau, 1988). These small differences in resonant frequency, or chemical shift, make it possible to differentiate molecules based on their distinct spectral signatures (e.g., Figure 1, 1 H spectrum; Figure 2, 31 P spectrum).…”
Section: Mrsmentioning
confidence: 99%