M5X3 intermediate phases formed by Ca, Sr and Ba

Bruzzone, G.; Franceschi, E.; Merlo, F.

doi:10.1016/0022-5088(78)90089-9

Cited by 79 publications

(30 citation statements)

References 16 publications

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“…The other compounds SrIn5, SrIn3, Sr2In5, Sr2In3, SrIn and Sr3In2 were formed via the peritectic reactions. Later Bruzzone et al [3] reported a Sr5In3 phase instead of Sr3In2 and determined the crystal structure of Sr5In3 to be Cr5B3 type crystal by single crystal and powder techniques and in the work of Wang et al [1] the Sr5In3 phase was considered instead of Sr3In2, which was consistent with the assessment of Okamoto [4].…”

Section: Introductionsupporting

confidence: 62%

Ab-Initio Reinvestigation of the (Sr-In) Binary System

Beddiaf¹,

Djaballah²,

Bouderba³

2015

IJAPM

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Sr-In intermetallics were studied by first-principles calculations within density functional theory (DFT) with the projector augmented-wave technique (PAW) and the generalized gradient approximations (GGA) as implemented in the ABINIT code. Six intermetallics: SrIn5, SrIn3, SrIn2, SrIn, Sr5In3 and Sr3In were investigated in their observed experimental structures. The lattice constants, enthalpies of formation and bulk modulus of the Sr-In intermetallics have been calculated. The calculated lattice constants and enthalpies of formation are in good agreement with experimental and other theoretical results.

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Section: Introductionsupporting

confidence: 62%

Ab-Initio Reinvestigation of the (Sr-In) Binary System

Beddiaf¹,

Djaballah²,

Bouderba³

2015

IJAPM

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“…Apart from CaZn 2 , CaZn 5 and CaZn 11 , all compounds undergo peritectic decomposition. Later on, the compounds Ca 7 Zn 4 and Ca 7 Zn 20 designated by [46] were replaced with Ca 5 Zn 3 and CaZn 3 , respectively, based on the more accurate crystallographic investigations of Bruzzone et al [47] and Fornasini and Merlo [48] and these will be used in the present optimization.…”

Section: Phase Diagrammentioning

confidence: 99%

Critical assessment and thermodynamic modeling of the binary Mg–Zn, Ca–Zn and ternary Mg–Ca–Zn systems

Wasiur-Rahman

Medraj

2009

Intermetallics

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“…Compounds M X with M"Ca, Sr, Ba and X"Bi, As, Sb were found to be tetragonal (7}9) Compounds M Bi with M"Ca, Sr, Ba have been the most studied: Ba Bi (8, 10) was described as orthorhombic with the -Yb Sb structure-type and Ca Bi hexagonal (11) with the Mn Si structure-type. The isostoichiometric compound Sr Bi displays the two crystallographic hexagonal (8) and orthorhombic (10) structures. The study of compounds M X , M"Ca, Sr, Ba and X"Bi, Sb, and their reactivity toward halogens and sulfur (12) was carried out later.…”

Section: Introductionmentioning

confidence: 99%

“…The intermetallic compounds Sr 11 Bi 10 , Ba 11 Bi 10 , and (Sr 5 Ba 6 )Sb 10 have been obtained from melts of mixtures of the elements. They crystallize in the tetragonal system, space group I4/mmm, Ho 11 Ge 10 structure type, tI84 Pearson symbol, Z ‫؍‬ 4, with cell parameters a ‫؍‬ 12.765(3), 13.230(3), 12.748(2) A s and c ‫؍‬ 18.407(3), 19.365(3), 18.761(2) A > , respectively.…”

mentioning

confidence: 99%