Lycia

Yağci, Emel Erten

doi:10.1093/gao/9781884446054.article.t052587

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Novel Photo-and Electro-controlled Methods Of Polymerization1

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2020

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“…The traditional Brønsted or Lewis acids-based initiating systems can be replaced with the systems capable of the controlled release of initiating cations under external stimuli (light, electrical, chemical, etc.) [137]. A number of recently introduced photoinitiating systems comprise functionalized carbazoles [141,142], pyrenes [143], di-and polythiophenes [144] and disulfones [145], C 60fullerene [146], allylic ammonium or phosphonium salts [147,148], acylgermanes [149] or different dyes [150,151] Scheme 21.…”

Section: Novel Photo-and Electro-controlled Methods Of Polymerizationmentioning

confidence: 99%

Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers

Kirillov

Rodygin

Ananikov

2020

European Polymer Journal

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This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo-and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.

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