Luminescent Tetranuclear Copper(I) and Gold(I) Heterobimetallic Complexes: A Phosphine Acetylide Amidinate Orthogonal Ligand Framework for Selective Complexation
Shubham,
Vanitha R. Naina,
Peter W. Roesky
Abstract:The synthesis of phosphine acetylide amidinate stabilized copper(I) and gold(I) heterobimetallic complexes was achieved by reacting ligand [{Ph2PC≡CC(NDipp)2}Li(thf)3] (Dipp = N,N’‐diisopropylphenyl) with CuCl and Au(tht))Cl, yielding the eight membered ring [{Ph2PC≡CC(NDipp)2}2Cu2] and the twelve membered ring [{Ph2PC≡CC(NDipp)2}2Au2]. {Ph2PC≡CC(NDipp)2}2Cu2] features a Cu2 unit, which is bridged by two amidinate ligands, served as a metalloligand to synthesize the heterobimetallic CuI/AuI complexes [{(AuX)Ph… Show more
In this work, coumarin-substituted phosphinoamine gold(i) chloride complexes were synthesized. Further reactions with KOtBu led to isolation of unexpected cyclic rings, which were investigated for their luminescence properties and reactivity.
In this work, coumarin-substituted phosphinoamine gold(i) chloride complexes were synthesized. Further reactions with KOtBu led to isolation of unexpected cyclic rings, which were investigated for their luminescence properties and reactivity.
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