“…Firstly, Sr 10 (PO 4 ) 6 X 2 (X ¼ F, Cl, Br) are well-known hosts for functional rare earth ions with subsequent applications as uorescent and laser materials. [24][25][26][27][28][29][30] Secondly, Sr 10 (PO 4 ) 6 F 2 (Sr-FAP) is of interest in biological elds because of the ready entry of Sr into the food chain and its subsequent incorporation in bone. [31][32][33][34] Thirdly, as the member of apatite family, Sr 10 (PO 4 ) 6 X 2 (X ¼ F, Cl, Br) are considered to be suitable for nuclear waste storage, such as the glass encapsulated Sr 10 (PO 4 ) 6 Cl 2 (Sr-ClAP) can immobilize most of the radwaste elements in the composite matrix.…”
A theoretical investigation on the structural stability, electronic, vibrational, and thermodynamic properties of the strontium apatites Sr10(PO4)6X2 (X = F, Cl, Br) is systematically conducted by the first-principles calculations.
“…Firstly, Sr 10 (PO 4 ) 6 X 2 (X ¼ F, Cl, Br) are well-known hosts for functional rare earth ions with subsequent applications as uorescent and laser materials. [24][25][26][27][28][29][30] Secondly, Sr 10 (PO 4 ) 6 F 2 (Sr-FAP) is of interest in biological elds because of the ready entry of Sr into the food chain and its subsequent incorporation in bone. [31][32][33][34] Thirdly, as the member of apatite family, Sr 10 (PO 4 ) 6 X 2 (X ¼ F, Cl, Br) are considered to be suitable for nuclear waste storage, such as the glass encapsulated Sr 10 (PO 4 ) 6 Cl 2 (Sr-ClAP) can immobilize most of the radwaste elements in the composite matrix.…”
A theoretical investigation on the structural stability, electronic, vibrational, and thermodynamic properties of the strontium apatites Sr10(PO4)6X2 (X = F, Cl, Br) is systematically conducted by the first-principles calculations.
“…Recently, UV (350-410 nm) LED chip mounted with blue, red, green or blue, yellow phosphor is considered as a promising white light generation way [2,3]. However, the samples in the previous works were fabricated by mixing two or three different phases of phosphors, leading to both a decrease in luminous efficiency due to re-absorption and poor reproducibility [4]. Thus, a single-phased phosphor for UVpumped white LED is required to enhance luminous efficiency and reproducibility of white LED.…”
“…The d–d transition in Mn 2+ is forbidden and difficult to be pumped whereas Eu 2+ has been demonstrated to be an efficient sensitizer for Mn 2+ . Guo et al reported energy transfer between Eu 2+ and Mn 2+ in the host Sr 5 (PO 4 ) 3 Cl 11. They also reported Eu 2+ ‐ and Mn 2+ ‐co‐doped Ca 5 (PO 4 ) 3 Cl with blue and orange double band emission 12.…”
Vanadium carbide incorporated on resorcinol–formaldehyde resin carbon (V8C7@RFC) was synthesized as a novel mesoporous catalyst‐support material by pyrolysis of the resorcinol–formaldehyde resin and NaVO3 mixture. The material’s BET surface area was 564 m2 g−1 and thus much higher than that of 389 m2 g−1 for the carbon powders yielded by resin carbonation. Physical characterization revealed that the supporting material possesses a mesoporous structure and Pt nanoparticles are homogeneously dispersed on the V8C7@RFC surface. Electrochemical measurements demonstrated that the V8C7‐modified Pt catalyst exhibits a negative shift of over 100 mV in the onset potential for COads electrooxidation and a dramatically enhanced activity in methanol oxidation reaction. The enhancement was mainly attributed to the electronic effect between Pt and V8C7 and the mesoporous structure providing ideal anchor sites for Pt dispersion.
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